This work deals with the preparation, characterization and kinetic studies on base hydrolysis of some Fe(II) Schiff base amino acid complexes.The prepared complexes were found to be of 1&… Más…
This work deals with the preparation, characterization and kinetic studies on base hydrolysis of some Fe(II) Schiff base amino acid complexes.The prepared complexes were found to be of 1:2 or 1:1 stoichiometry and non - electrolytic character, solubility measurements of these complexes showed them as hydrophobic in nature. The base hydrolysis reaction of the prepared complexes was carried out in aqueous, co-organic media and in the presence of added salts. The kinetic measurements confirmed the pseudo 1st - order rate dependence in [complex] and 2nd - order in [OH-]. A relevant mechanism was suggested in which the parallel attack of OH- ion on the central Fe(II) atom and the dissociation of the first ligand is provided as rate - determining step. The observed decrease of base hydrolysis rate constant kobs. with increasing the mole fraction of co-organic solvent indicates solute - solvent interaction between delocalized charge in complex and dispersion centers on solvent molecules. Trade Books>Trade Paperback>Science>Chemistry>Chemistry, LAP Lambert Academic Publishing Core >1<
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This work deals with the preparation, characterization and kinetic studies on base hydrolysis of some Fe(II) Schiff base amino acid complexes.The prepared complexes were found to be of 1&… Más…
This work deals with the preparation, characterization and kinetic studies on base hydrolysis of some Fe(II) Schiff base amino acid complexes.The prepared complexes were found to be of 1:2 or 1:1 stoichiometry and non - electrolytic character, solubility measurements of these complexes showed them as hydrophobic in nature. The base hydrolysis reaction of the prepared complexes was carried out in aqueous, co-organic media and in the presence of added salts. The kinetic measurements confirmed the pseudo 1st - order rate dependence in [complex] and 2nd - order in [OH-]. A relevant mechanism was suggested in which the parallel attack of OH- ion on the central Fe(II) atom and the dissociation of the first ligand is provided as rate - determining step. The observed decrease of base hydrolysis rate constant kobs. with increasing the mole fraction of co-organic solvent indicates solute - solvent interaction between delocalized charge in complex and dispersion centers on solvent molecules. Trade Books>Trade Paperback>Science>Chemistry>Chemistry, LAP Lambert Academic Publishing Core >1<
new in stock. Gastos de envío:zzgl. Versandkosten., más gastos de envío
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Detalles del libro - Kinetic Features of the Base Hydrolysis of Schiff Base Complexes Lobna Abdel Nassr Author
EAN (ISBN-13): 9783848482276 ISBN (ISBN-10): 3848482274 Tapa dura Tapa blanda Año de publicación: 2012 Editorial: LAP Lambert Academic Publishing Core >1
Libro en la base de datos desde 2008-11-22T05:54:02-06:00 (Mexico City) Página de detalles modificada por última vez el 2024-04-15T09:47:16-06:00 (Mexico City) ISBN/EAN: 9783848482276
ISBN - escritura alterna: 3-8484-8227-4, 978-3-8484-8227-6 Mode alterno de escritura y términos de búsqueda relacionados: Autor del libro: mohsen Título del libro: base, schiff
